Kindly try to use as below:
declare @employeeData xml --this would be your XML input parameter
set @employeeData = '<employeeData>
<employee LastName="Smith" FirstName="Randolph" EmployeeID="1234567"/>
</employeeData>'
declare @xmlTable table (LastName nvarchar(255), FirstName nvarchar(255), EmployeeID int)
insert into...