I think the question has been written incorrectly.
select myOrd.Order_No, myiT.Item_No, myOrd.Unique_ID as 'UniqueID'
FROM myOrders myOrd
JOIN myItems myiT
ON myOrd.Order_No = myiT.Order_No
Order BY myiT.Unique_ID desc
select myOrd.Order_No, myiT.Item_No, myOrd.Unique_ID as 'Unique_ID'
FROM myOrders...