If you mean, can you generate a word document from a SQL query, then I guess the short answer is "yes".

Try:

WITH XMLNAMESPACES ('http://schemas.microsoft.com/office/word/2003/wordml' AS W,

'urn:schemas-microsoft-com:office:office' AS o)

SELECT 'Hello World!' AS...

As other posters have pointed out, you will need the child-parent relationship from your relational database tables to construct the XML hierarchy. Try this:

-- Create table, but this time add...