Do you mean you have a Word document you want linked with a record?
You can store the Word file in an image column in SQL Server, but you'd need to stream it out to your application and handle the printing. That's an application issue (loading Word document in memory) and not something you'll probably get an answer here to.
You can also store a path in the database to the file. Then your application and read the path and open the file. Again, a programming issue, not a SQL Server one.