On thing you can try is to stop and restart the mirroring endpoint. This sometimes wakes up the mirroring and it will start trying to catch up - To list all endpoints in a SQL Server instance, you can query sys.endpoints catalog view that contains one row for each endpoint:
select * from sys.endpoints
--
To stop an endpoint:
ALTER ENDPOINT endpoint_name STATE = STOPPED
--
To start an endpoint:
ALTER ENDPOINT endpoint_name STATE = STARTED